منابع مشابه
Solar synthesis: prospects in visible light photocatalysis.
Chemists have long aspired to synthesize molecules the way that plants do-using sunlight to facilitate the construction of complex molecular architectures. Nevertheless, the use of visible light in photochemical synthesis is fundamentally challenging because organic molecules tend not to interact with the wavelengths of visible light that are most strongly emitted in the solar spectrum. Recent ...
متن کاملVisible Light Photocatalysis of 6π Heterocyclization
Photo-mediated 6π cyclization is a valuable method for the formation of fused heterocyclic systems. Here we demonstrate that irradiation of cyclic 2-aryloxyketones with blue LED light in the presence of an IrIII complex leads to efficient and high yielding arylation across a panoply of substrates by energy transfer. 2-Arylthioketones and 2-arylaminoketones also cyclize effectively under these c...
متن کاملIncreasing visible-light absorption for photocatalysis with black BiOCl.
Black BiOCl with oxygen vacancies was prepared by UV light irradiation with Ar blowing. The as-prepared black BiOCl sample showed 20 times higher visible light photocatalytic activity than white BiOCl for RhB degradation. The trapping experiment showed that the superoxide radical (O(2)(•-)) and holes (h(+)) were the main active species in aqueous solution under visible light irradiation.
متن کاملPlasmon enhanced visible light photocatalysis for TiO2 supported Pd nanoparticles.
A photocatalyst consisting of nanostructured Pd photochemically deposited on 20 nm TiO2 displays a reaction half-life for rhodamine b decolourisation of 0.5 minute compared to the 9.4 minutes for unmodified P25 under identical reaction conditions. We associate this increased decolourisation rate to the increase in solar light harvesting which we have measured at 8% due to a significant red shif...
متن کاملNanostructure sensitization of transition metal oxides for visible-light photocatalysis
To better utilize the sunlight for efficient solar energy conversion, the research on visible-light active photocatalysts has recently attracted a lot of interest. The photosensitization of transition metal oxides is a promising approach for achieving effective visible-light photocatalysis. This review article primarily discusses the recent progress in the realm of a variety of nanostructured p...
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ژورنال
عنوان ژورنال: Nature Photonics
سال: 2012
ISSN: 1749-4885,1749-4893
DOI: 10.1038/nphoton.2012.15